Category Archives: Book

Nanocellulose Experiments in Art Conservation

Becoming Familiar with Nanocellulose

These days, nanocellulose can be found in everyday products, like compostable plastic-like bags; however, the use of nanocellulose is still in its infancy in terms of research and use in art conservation. (For example, these decomposable poop bags look like plastic bags, but can actually be tossed in your compost pile!)

Introduction

This post takes a look at how nanocellulose films might be used in art conservation. To dip our toes in, experiments at the Cincinnati Art Museum were performed with a group of conservators who work in different specialties: textiles, objects, fine art, photographs and bound materials. We tried out various types of nanocellulose films and how they might be applied to a range of materials.

Laura shows the high degree of translucency of the crystalline films she made in Indianapolis at a prior workshop

Cecile examines repairs on a war bond poster

What is Nanocellulose?

Nanocellulose is made up of nanoscale cellulose particles that come from different sources, like:

Wood: The most common source
Non-Wood Plants: Cotton, ramie, sisal, bamboo, and agricultural by-products. The decomposable poop bags mentioned above are made from corn starch nanoparticles!
Tunicates: Marine invertebrates, the only animals known to produce cellulose microfibrils.
Algae: Some species produce cellulose microfibrils within their cell walls.
Bacteria: Certain bacteria, like Gluconacetobacter xylinus, can produce cellulose microfibrils under the right conditions.

Types of Nanocellulose:

In conservation, the field has been experimenting with two main types:

Microfibrillated Cellulose (MFC): A mix of cellulose microfibrils from pre-delignified cellulosic materials. This type of nanocellulose appears cloudy once dispersed into a film format.

2. Cellulose Nanocrystals (CNC): Composed solely of the crystalline part of cellulose, exhibiting high crystallinity and a high aspect ratio. This type of nanocellulose appears clear in a cast film.

Where to Buy

Many labs and companies around the world make nanocellulose products like gels, nanopapers, and foams. Here are a few:

Europe: Technical Center of Paper (CTP, France), EMPA (Switzerland), Weidmann Fiber Technology (Switzerland), Aalto University (Finland), VTT Technical Research Center of Finland, KTH (Sweden)
North America: The University of Maine (USA), Forest Products Lab, Wisconsin (USA), American Process Inc., Atlanta (USA), Celluforce (Quebec), Kruger Inc. (Quebec)
Asia: University of Tokyo, University of Kyoto, Asahi Kasei

What We Bought

In Cincinnati, we experimented with two products purchased from Weidmann Fiber Technology in Switzerland:

Celova for Art Conservation, 500g Gel: According to the Weidman Fiber Technology website, the gel has a high degree of fibrillation and is recommended for technical applications like art conservation.

Celova MFC powder, 150 g: The powder is suggested for waterless and water-free applications.

During practical applications, the MFC powder did not react the same way as the gel during the film creation. The powder precipitated out and did not cast a homogeneous film.

Cecile’s initial tests with Solka-Floc Powdered Cellulose from Solvaira Specialties. It is a very fine, highly purified cellulose powder made from bleached wood pulp.

While it may have been a mistake in our method of production, my guess is the powder isn’t as well fibrillated for casting and wonder if that’s why it stayed out of solution.

Next, I am eager to try the CNC form, which appears to be available at https://umaine.edu/pdc/nanocellulose/.

What makes nanocellulose films unique?

High Purity and Stability: They’re almost pure cellulose, super stable, and have a neutral pH. They’re less affected by temperature and humidity than regular paper.

Strong Yet Delicate: Mechanically, they’re stronger than traditional paper in some ways but less elastic and easier to tear.

Remarkable Transparency: The nanoscale dimensions of the fibers eliminate light scattering, resulting in highly transparent films, often called “nanopapers.” The transparency is influenced by the film’s structural density, particle size (MFC or CNC), the source material, and the manufacturing process. In practice, this transparency reminded me of the appearance of glassine tape.

How are nanocellulose films made?

There are various ways to make nanocellulose films, but conservators use one main method (as the others are found in larger scale manufacturing processes).

Casting Film by Evaporation: A low-cost and easily reproducible method where a nanocellulose solution is cast onto a substrate like a silicone mold or a polystyrene petri dish, allowing the solvent to evaporate. This technique produces homogeneous films.

Interestingly, it took an extraordinary amount of time for the solvents to evaporate at the Cincinnati Art Museum. Even after placing the trays in a fume hood to encourage drying, it took many days for the films to form during a low RH in December!

Glass and polyester dishes are not recommended for casting onto as the films will not release from these containers.

**What are nanocomposite films?**

Simply put, nanocellulose is combined with an adhesive. During the film’s creation, the adhesive is added into the nanocellulose solution to enhance the film’s physical and optical properties. Common conservation adhesives added to films include Klucel G, wheat starch paste, methyl cellulose, and gelatin.

In our experiments, we used 5% Klucel G, 4% Methocel A4CP, and strained Zen Shofu wheat starch paste. Two batches were made of varying amounts of gel to see if there was a difference in thickness of the films (spoiler: I couldn’t tell a noticeable difference!).

For another batch, Cecile also added in some QoR Golden watercolors that have an aquazol-based binder for a bit of a brown-toned tint that might be handy for filling losses in photograph conservation.

Nanocomposite films created with 20ml of MFC gel with 5% Klucel G and 5% methocel added

Nanocomposite films created with 15ml of MFC gel with 5% Klucel G and 5% methocel added

Nanocomposite film with QoR raw umber and 25% Methocel

Applications of nanocellulose films in art conservation:

Nanocellulose film properties may be handy for use in art conservation for their:

High transparency and stability. Used as a repair material, the films blend into substrates and supporting fragile artifacts.
Compatibility with various adhesives
Minimal discoloration after aging ensures long-term stability and visual integrity of treated artworks.
Reversibility. They can be safely removed if needed.

Limitations to using nanocellulose films in conservation:

While promising, there are some downsides to consider:

Lower tear strength compared to traditional paper. The films are delicate and might not work for items that need to withstand a lot of use.
Water Sensitivity: the films are highly reactive to moisture and require different application repair techniques than traditional paper repairs. For me, I wondered if the amount of time required for the learning curve of successful application was worth the result over traditional paper repairs.
Long-term behavior of nanocomposite films and their interaction with art materials requires further research to ensure compatibility and prevent unintended consequences.

Testing the Films on Paper-Based Materials

Both pure nanocellulose films and nanocomposite films were tested on a non-collection items using a variety of techniques.

Pure films were applied with a range of adhesives while nanocomposite films were adhered either by remoistening/reactivating with solvents or adhered by applying additional adhesive to the film, in addition to what was mixed in during the casting.

While Cecile worked on a war bond poster, Obie worked on a garment, and Laura tested treatment on an ink jet print, I tried my luck on a map.

Together, we all tested a scrapbook owned by Kelly.

First applications on a dark and brittle substrate surprisingly reminded us of the appearance of glassine tape in specular light!

After multiple tries, Cecile impressed me with her application in the red “u” that blends in better than in the black and yellow regions on the war bond poster

My Successful Applications

I had best luck with the nanocomposite films but only when they were reactivated with the adhesive they were made with.

I used a map for a variety of tests on one item to compare results

For example, the 20 ml 0.2% MFC gel created with 0.6 g 5% methocel film blended beautifully into the paper when reactivated with 5% methocel. The methocel was brush applied thickly. See the repair below along the left side in specular light. It doesn’t even look like tape here! The repairs blend nicely. Between the two, I found the methocel nanocomposite film blended better than the wheat starch paste.

Repair on far left: Nanocomposite film made with 5% methocel was reactivated with brush application of 5% methocel.

My second favorite options were the pure MFC films adhered with methocel and wheat starch paste.

My Application Failures

I could not for the life of me find a way to successfully apply the nanocomposite film with Klucel G to a paper substrate without it falling apart during the process. Cecile had better luck while for me, it stuck to everything! I struggled both when it was reactivated with ethanol and when the film was brushed with the Klucel G solution. Plus, it was super shiny and didn’t help the paper lie flat.

Shiny repair on far left: Nanocomposite film made with 5% Klucel G was reactivated with dip in ethanol

I had even worse luck with the nanocomposite films when they were only reactivated with water. I could easily apply them to the paper, however, these performed the worst out of all the repairs, with the methocel nanocomposite film failing to even hold the tear together! See the two center repairs below in specular light. The wheat starch paste held, but didn’t want to hold the tear well aligned.

Failed repair in center: nanocomposite film with 5% methocel reactivated with water before adhering

Compared to kozo tissue repairs (on the same paper): the nanocellulose repairs overall were shinier (more akin to glassine tape in appearance!), but they didn’t seem to cause any planar distortions like the kozo tissue naturally wants to do. However, the kozo tissue blends visually into the paper better. The kozo tissue repairs are the ones with the tails sticking off the edge of the paper.

Repair on left: nanocomposite film made with 5% methocel applied with 5% methocel almost has a glassine tape-like appearance. Repairs on right with tails sticking off paper: traditional kozo paper repairs adhered with wheat starch paste

Conclusion:

Nanocellulose films offer promising potential for art conservation but require a learning curve to handle and apply. Their unique properties, combined with ongoing research and development, could lead to innovative solutions for preserving cultural heritage, but research on long-term stability, compatibility with specific artwork materials, and ethical considerations will be crucial for wider adoption in the field.

Health and Safety:

Pure nanocellulose gels and films are generally considered safe to handle.

Resources

Most of the info here comes from resources shared by paper conservator, Cecile Mear who organized our informal experimentations. Photograph Conservator, Laura Moeller also provided additional resources she gathered from a workshop held at the Indiana Historical Society in June 2019.

bpga36-20.pdf Detailed introduction to nanocellulose films use in conservation
Full article: A New Mending Material: Nanocellulose Film
Nanocellulose Films in Art Conservation: A New and Promising Mending Material for Translucent Paper Objects
bpga42-01.pdf Photograph conservation
bpga41-01.pdf Fan conservation treatment—application of nanocellulose in gel form
YouTube video: Practical techniques for creating nanocellulose film and the application of aqueous adhesives.
Canham, R. ” Nanocellulose Calculator.” Burr Oak Bookbinding. Article related to YouTube video.
Heritage Science. “Nano meets the sheet: Adhesive-free application of nanocellulosic suspensions in paper conservation.” Full Text.
Heritage Science. “New treatments for canvas consolidation and conservation.” Full Text.
Heritage Science. “Novel nanomaterials to stabilise the canvas support of paintings assessed from a conservator’s point of view.” Full Text.
Pinkney, J. “Nanocellulose for Conservation.” University of Birmingham.

Ashleigh Ferguson Schieszer – Special Collections Library Conservator

Variety of experimental tests. The reticulated dishes contain the MFC powder while the homogeneous films were created using the gel.

Historical Binding Structures with Julia Miller

This week the Preservation Lab and the Archives and Rare Books Library hosted a 2-day workshop with the conservator and book historian Julia Miller. The workshop, Identifying and Describing Historical Binding Structure: A Stacks Appraisal Workshop, provided the Preservation Lab staff, University of Cincinnati Libraries’ (UCL) special collections catalogers, and UCL special collections stewards an opportunity to strengthen their skills of historical binding identification and description. We honed our descriptive skills by examining collections from the Archives and Rare Books Library and models/exemplars from Julia’s personal teaching collection.

Julia Miller is in the fore ground holding a highly decorated book that is read with gold stamping and tooling. — Julia Miller presenting to the Historical Binding Structures class.

Thanks to Julia Miller, one of the most knowledgeable and giving people that we have had the privilege to learn from.

Thanks to Chris Harter for providing access to so many Archives and Rare Book treasures and a wonderful space to learn and collaborate.

Thanks to Catarina Figueirinhas for suggesting the course and being the on-site coordinator and organizer.

Lastly, thanks to University of Cincinnati Libraries for their continued support of staff professional development!

Holly Prochaska [UCL] — Preservation Librarian

Problem Solving: An Exhibition-Style Enclosure for a Collection of Lafcadio Hearn Japanese Bindings

This set of Japanese side-sewn, crepe paper bindings, or Chirimen-bon, came to the Preservation Lab housed in their damaged traditional Japanese wraparound case, known as a maru chitsu. The set belongs to the Cincinnati and Hamilton County Public Library, which has an extensive Lafcadio Hearn collection. This collection of volumes was printed by Hasegawa Takejirō, a Japanese publisher who specialized in books written in European languages on Japanese subjects. The Japanese Fairy Tale Series was one of the more popular series, beginning with six volumes in 1885; though this later collection only has five volumes of fairy tales. Lacadio Hearn was one of the foreign translators employed by T. Hasegawa.

Original enclosure laying on a table — Original enclosure

Five volumes withing the original enclosure, the enclosure is open — Original enclosure

Due to the high profile nature of Lafcadio Hearn for the library and the beauty of the bindings, the collection is often shown during tours and used for display, however, the crepe paper volumes, while in excellent condition, are extremely floppy, and they are also side-sewn, both factors make them difficult to handle and display. The original enclosure is also very fragile and damaged, and susceptible to further damage if used as an enclosure moving forward. For all these reasons, the curators wanted an enclosure that would not only store the collection long-term, but could also be used for display.

This proved to be a challenge, but a fun one. I started by making a couple of sketches and then a couple of models…

Three models pictured, two are collapsible cradles and one display stand with foam insert — Models – two types of collapsible cradles and one model of the display tray/stand

For the models, I had two main focuses: 1) a collapsible cradle that would house and display one of the volumes, and 2) a display component that would act as a tray or level within the enclosure and house the remaining four volumes, in two stacks of two, side by side.

I will always advocate for making a model if you are trying to work through a new enclosure or adjust an existing enclosure or display piece, like a cradle. For example, I knew that a normal collapsible cradle wasn’t going to fit the bill for these volumes. Instead, I was going to need a stiff, squared off spine piece built into the cradle to help support the bindings’ spines.

Closed collapsible cradle with volume inside — Closed collapsible cradle

Collapsible cradle opened, detailed image showing the spine support piece of the cradle, with volume inside — Closed collapsible cradle

One of the main areas I had to troubleshoot was the display tray, which would house the four remaining volumes. I knew I wanted to create a stand that would basically replicate one side of a collapsible cradle and have a 1/2 inch Plastazote foam insert, which happened to nestle the thickness of two volumes perfectly, that was covered in Tyvek. But I had concerns about gravity and reliability of PVA to hold the foam insert in place overtime. And I wasn’t happy with my initial ideas of how to remove the volumes (and also the original enclosure and collapsible cradle) from the insert(s), which consisted of a tab underneath the volume. It created friction that would ultimately cause damage to the actual volumes.

Ultimately, I am extremely happy with what I came up with. I think it functions very well, and checks all the boxes it needed to check. Safe, secure storage. Elegant display. User-friendly.

Display tray open, with four volumes in it, two volumes are visible and on display — Display stand open

Detail image of the display tray — Display stand open

The display stand includes a cloth tape inserted into the boards to keep it from opening too far, a foam insert covered in Tyvek, a lip to support the foam insert overtime, and two polyester film slings to aid in removing the volumes from the foam insert. The polyester slings proved to be an excellent solution for removing all the elements from the enclosure safely and easily.

For those interested in how some of the components were constructed, here are some in-progress images…

Photo showing the display stand being made — Detail of the turn-in for the display stand lip; cut similarly to how we cut our clamshell enclosure tray turn-ins

Foam insert being covered in Tyvek — Foam insert, vertical panels covered in Tyvek first

Tyvek cut in preparation for covering the foam — Foam insert, vertical panels covered in Tyvek first

Because of the way the trays/components of the enclosure are constructed, they are actually interchangeable. So if the “lower tray” with the original enclosure and collapsible cradle ends up on top of the display tray/stand, that’s not an issue at all. And there is a 1/4 inch Volara foam piece adhered to the outer tray of the clamshell enclosure, so whatever items are on top will be cushioned by soft foam in the enclosure.

Get a full tour of the enclosure by watching our reel on Instagram:

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Jessica Ebert [UCL] – Assistant Conservator

Nests and Eggs on Display at the Cincinnati Symphony Orchestra

Illustrations of the Nests and Eggs of Birds of Ohio are on display at the Cincinnati Symphony Orchestra March 1^st and 2^nd as part of a musical program honoring Oliver Messiaen who was both a major composer of the 20^th century and an ornithologist.

Synesthesia

Oliver Messiaen is well known for studying bird songs and interpreting their notes into musical transcriptions. His works are also unique in that Messiaen experienced synesthesia which greatly influenced his creations. Synesthesia is when a person perceives more than one sense at a time, such as Messiaen who experienced colors when listening to music and was able to see sounds.

Cincinnati Symphony Orchestra Program

The program at the CSO honors Messiaen by incorporating both music, color, and bird visuals to invite the audience to experience a unique multi-sensory experience. Messiaen’s Des canyons aux étoiles (“From the Canyons to the Stars”) will be performed by the conductor, Matthias Pintscher, and pianist Pierre-Laurent Aimard.

Click the image for a link to the digital program for the CSO Proof: *From the Canyons to the Stars*

“Inspired by his visits to Utah’s Bryce Canyon and Zion National Park, Messiaen’s Des canyons aux étoiles (“From the Canyons to the Stars”) depicts the birdsong and red rock hues he experienced during his time in the desert… Accompanied by immersive video-art, Springer Auditorium will be transformed, allowing listeners to escape into the southwestern landscape and experience a synesthesia of their own.” – As described by the CSO website

Nests and Eggs

Complementing the musical performances, on display will be a page from Cincinnati and Hamilton County’s Illustrations of the nests and eggs. The page showcases a local Ohio native, the Wood Thrush, who lays bright blue colored eggs within a nest made of old leaves, dried grasses and moss (rarely sticks). The nest of the Wood Thrush also contains “rootlets” placed intentionally inside of the nest, resulting in a pinkish brown or black lining. The nest is “plastered” with a thin mud that is easily missed as it’s thoroughly worked in and covered.

Nests and Eggs, while lesser known than Audubon’s Birds of America, is quite extraordinary in how it highlights the uniqueness of the construction of nests made by different bird species. Take for instance, the Baltimore Oriole’s nest, which primarily consists of strings and flax fibers to create a soft and long pocket. Compare that to the more traditional nest of the Wood Thrush whose home is bowl-shaped with a wide opening.

It’s also extraordinary that the illustrations are detailed lithographic portraits created by Gabrielle Estelle Jones and her family, despite not having been formally trained. Their work was intended to be used as a companion volume to John James Audubon’s Birds of America. While not as large as the Birds of America double elephant folios, Eggs and Nests is still an impressively large-sized volume.

Gabrielle “Gennie” Estelle Jones

The following excerpt was written by Sara Williams, Arts & Special Collections Reference Librarian:

Illustrations of the Nests and Eggs of Birds of Ohio was a project begun by Genevieve Estelle Jones, a native of Circleville, Ohio. Born May 13, 1847, Genevieve, or Gennie, spent much time as a young girl birdwatching in the woods and wetlands with her father, an amateur ornithologist. Just before the age of 30, Jones’ father forbade her from marrying the man she loved, and in 1876, she visited the Centennial World’s Fair in Philadelphia to take her mind off her broken heart. While there, she viewed hand-colored engravings from John James Audubon’s vibrant The Birds of America. Inspired by Audubon’s example, Jones set out to illustrate the nests and eggs of birds, an aspect often missing from his work. Jones completed only five illustrations for her book before she died of typhoid at the age of 32. The work was eventually completed by Genevieve Jones’ family. Only 90 copies of the book were published, of which only 34 are currently known to exist.

Preservation

As part of the Preservation Lab’s role in displaying the object, a condition report book was created to accompany the item to ensure the object’s condition is preserved. This helps those who are installing anticipate any possible challenges in supporting fragile pages or bindings. In this case, the upper endsheets are extremely brittle and have been previously repaired, but could break again if not carefully draped and held with polyester strapping in a safe manner.

After determining a proper exhibit case to fit and secure the binding, a custom cradle was made. To protect weak points of the binding on display, a support was constructed out of 8 ply museum mat board to support the heavy and oversized pages from stress along the joint.

Solutions were tested to fit within an 18 inch deep case, however, the book was just too large!

A custom 8 ply mat board cradle was created to fit within a more appropriate 4 ft case. Pages are strapped with polyester strapping

Before an object travels, it’s often reviewed to make sure it can handle transport and treated if necessary. Luckily, in this case, the binding was treated in 2016 and is still in great condition for its age. When it received treatment, at that time it received a lightweight yet strong enclosure that will also work well to safely protect the item for travel to the CSO.

Corrugated banker’s box with a drop spine houses the Nests and Eggs book. Binding and exhibit labels are ready for packing.

A 4-foot case was kindly loaned to the CSO from the Behringer-Crawford Museum and is ready for use! (Image credit: Amber Ostaszewski)

Entrance to the Founder’s Room
Bird sounds were played in the entryway
During staging of the exhibit
Nests and eggs on display in the Founder’s Room
The Founder’s Room
Night of the performance
Entering the theatre
Not visible are the camping chairs and fire pits in the orchestra pit

Additional Resources

Interested in seeing more Nests and Eggs? The entire binding is conserved and digitized where it is made publicly available online. More information about Gennie’s fascinating and tragic history can be read at the Linda Hall website.

CSO Program Dates

There are two programs where you can view the item on display, Friday, March 1^st and Saturday, March 2^nd, both at 8pm at the Music Hall. Interested? Click here for the digital program.

We hope to see you there!

Ashleigh Ferguson Schieszer [CHPL] – Book and Paper Conservator, Co-Lab Manager

What ſay you! A brief look at the “long s” and its usage

Introduction To The Long S

I was recently building an enclosure for a book dating back to 1681 entitled The Experienced Farrier. While examining this item I noticed something interesting about the spelling of certain words: often, rather than seeing what normally should be the letter “s” I would see what appeared to be the letter “f.”

Figure 1: An image from The Experienced Farrier, containing what appears to be “strange” spellings.

Since noticing this, I started seeing these seemingly bizarre spellings in other items dating to this period, as can be seen in the title page from a copy of Don Quixote from 1678.

Figure 2: An image of the text from Don Quixote, with further examples of these “strange” spellings.

Identifying The Long S

After some sleuthing, I discovered something interesting: these letters were not “f”s at all. They were a now defunct character known as the “long s.” Closer examination of these letters in the text showed that, although they closely resembled an “f,” the horizontal cross bar did not extend all the way across the letter; it starts on the left side and ends in the middle.

Figure 3: A close-up of the word “most” that uses the “long s.” Note that the horizontal cross bar stops at the center stem of the letter.

Figure 4: The “long s” (left) as compared to a lowercase “f” (right).

This solved some of the mystery, but what about the characters that looked like an “f” where the bottom of it curves to the left?

Figure 5: Another style of the “long s,” depicted as it would appear in cursive handwriting.

The answer is that this is also a “long s,” but depicted how it was written in cursive. If you feel like you’ve seen this character before, you’re probably correct: a notable example of this style of “long s” can be found in the first line of the Bill of Rights. Some may also recognize this character from calculus as the “integral” symbol.

Figure 6: The “long s” that occurs in the word “Congress” as it appears in the handwritten Bill of Rights.

Figure 7: The “integral” symbol used in calculus uses the same character used for the cursive-style “long s.”

When The Long S Was Used

You may have noticed in some of these examples that not every “s” is the long form. So, what exactly were the rules for when and where this character was used?

It’s difficult to say exactly, as the rules changed over time and writers/printers didn’t always adhere to the same rules. However, according to a blog from the National Archives, some simple guidelines for when and where the “long s” was used are as follows:

An “s” would use the long form if it appeared at the beginning or in the middle of a word, but only if it is a lowercase s. An uppercase S would not use the long form of the letter.
An “s” would not use the long form if it was the last letter in a word.
It was very common in the case of a “double s” or “ss”, as in the word “opossum”, for both “s”s to be the long form (opoſſum), unless the “ss” ended the word, as in the word “congress”, in which only the first “s” would be the long form (congreſs). *

*An observant reader may notice that this last rule is redundant given the first two rules; however, mentioning the “long s” in the case of an “ss” is significant in that as this character fell out of favor with writers/printers, one of the last remaining circumstances that utilized it was in the case of an “ss.”

Figure 8: Examples of when the “long s” was/was not used.

Final Observations

Gradually, the “long s” fell out of usage around the time of the late 1700’s-1820’s, although it persisted longer in handwriting. Serendipitously, while writing this blog post, the lab received a first edition copy of Goblin’s Market with a handwritten note inside from the author, Christina Rossetti dating to 1862 that features this use even in the late 19th century:

Figure 9: Although difficult to read, this is the word success (ſucceſs) from a handwritten note dating to 1862 that utilizes the “long s” several decades after it fell out of common usage in printed media.

If you still find words containing a “long s” difficult to read, you aren’t alone; it has been theorized that it was phased out in favor of exclusive “short s” usage as they weren’t as easily confused with other letters and were found to be more legible. The disappearance of the “long s” is a good reminder that language, both written and spoken is fluid with ever evolving rules and norms.

Resources

For further information about the long s and its history be sure to check out these excellent blog posts, that were very helpful in the gathering of information for this post:

U.S. National Archives blog: https://prologue.blogs.archives.gov/2021/12/14/the-long-s/. Images Credits for the Bill of Rights belong to the National Archives at this link above.
Jeremy Norman’s History of Information: https://www.historyofinformation.com/detail.php?id=2344

Matt McCoy, Conservation Specialist [CHPL]

Fish gelatin: Spreading the word about a book conservator’s new friend

Last year around this time, the lab was fortunate to bring in book conservator and toolmaker, Jeff Peachey for a week-long intensive workshop to learn leather rebacking. While I always expect to walk away with new anticipated skills as advertised by the workshop, I’m ALSO always pleasantly surprised by the tangential tips and tricks shared along the way. In the case of Peachey’s workshop, there were many! One of my favorites was his use of a fish gelatin.

Introduction to Cold Fish Gelatin

While adhering spine linings to our text blocks, Peachey pulled out a small baggie of fish gelatin he brought with him to the workshop. He poured the dry flaky powder into a small jar, added room temperature cold water, and mixed it until a liquid-y consistency. He then added strained wheat starch paste to the gelatin and mixed with water until he was happy with the consistency. He estimated it was a 40:60 ratio of gelatin to paste.

Jeff Peachey taught a workshop at the Preservation Lab in Oct. 2022 where he first introduced us to a low-bloom fish gelatin for book conservation that didn’t require heat for use

If you’ve ever used gelatin before, you might be wondering – how is it possible to mix the gelatin without heating? That’s the beauty of this product – it has a high molecular weight with low bloom strength and is produced from cold water fish which gives it this ability. It might not be the strongest of the films with a 0-bloom strength, but for a book conservator doing paper repairs that need to be reversible yet strong, this combo still had an amazing tack when dry!

Peachey explained he first heard about the gelatin on a lab tour at the Weissman Center. He recalled Alan Puglia might have been the one who originally investigated the adhesive for pigment consolidation of hundreds of manuscripts for a show. The mention of a high molecular weight Norland fish gelatin was shared during a talk given at the American Institute for Conservation’s 44^th annual meeting. The talk was titled, The Challenge of Scale: Treatment of 160 Illuminated Manuscripts for Exhibition,” by Debora D. Mayer and Alan Puglia.

Peachey also doesn’t take credit for mixing the gelatin with wheat starch paste. He notes that even in Rene Matin Dudin’s 18^th century manual, it discusses the “union” of paste and glue in the last paragraph below.

Peachey shares an excerpt by Rene Matin Dudin descripting his 18^th century historic use of gelatin mixed with paste.

By the end of the week-long workshop, I had fallen in love with the properties of how well it adhered. By itself, the fish gelatin had a long working time and didn’t stick until it was nearly dry – but when mixed with wheat starch paste, it combined the best of both worlds. There was both the initial tack from the paste and a strong adhesion from the gelatin after dry. I wasted no time in ordering my own sample supply.

Treatments Testing the HMW Fish Gelatin

Over the past year, I’ve slowly incorporated the fish gelatin in treatments and testing more applications.

I first successfully used it to hinge-in heavy encapsulated sleeves into an album containing lung cross sections. After ultrasonically welding a paper hinge into an encapsulated sleeve, I applied the mix of wheat starch paste and fish gelatin to adhere the hinge to the scrapbook stubbing and had wonderful success. I was able to adhere with confidence that the encapsulation would stay in place and was able to avoid disbinding and resewing. At one point during treatment, I found I needed to reposition a hinge. I am happy to report the mixture was as easily reversible as wheat starch paste alone!

Ashleigh Ferguson Schieszer uses the 40:60 mixture of fish gelatin and wheat starch paste to hinge encapsulations into an album, ensuring the heavy encapsulations with paper hinges stay adhered.

Most recently, I played around with using it for photographic emulsion consolidation. I used it first as a barrier layer before inpainting, and then to add sheen to in-painted photograph regions that were originally matte in comparison to the surrounding gelatin coating. It seemed extremely easy to apply and clean up was less messy than other photographic gelatins I’ve used in the past. The sheen was just the right amount of gloss I needed without being overly shiny. And, best of all, no heat required.

Examples of photographic condition issues where the fish gelatin was tested: flaking emulsion was consolidated and a barrier layer was applied before inpainting

We’ve also used the gelatin to stabilze breaks in a wooden box originally used to house a Richter’s architecture game from the early 20^th century.

Jeff Peachey’ main use is to line spines. He’s found it not only has better adhesion than straight paste, but makes the spine feel slightly more solid and resistant to torsional forces

Applying fish gelatin to adhere spine linings

In the future, I imagine this gelatin would have excellent potential in media consolidation.

In all these uses, I couldn’t be more thrilled to not have to pull out my baby bottle warmer to set a beaker of gelatin on. As a result, there was no fuss in worrying about how long the gelatin was heated and if it was losing its properties due to heat.

*Example of using a baby bottle or coffee warmer to re-heat pre-made gelatin during typical use*

In terms of shelf life, the dried granules can be kept indefinitely like unmixed wheat starch paste. Once mixed, Jeff suggests that he’s found the adhesive properties hold up for about a week in the fridge; however, it does begin to smell fishy after just a day. So unlike wheat starch paste, if you’re adverse to the fishy odor, you’ll only want to make up as much as you’re planning to use for one day.

Supplier Info

Interested in getting your hands on some?

I found the product used at Weisman is no longer supplied by Norland – but I was able to track down what appears to be the same product through AJINOMOTO NORTH AMERICA, INC. If you’re interested in trying a sample, message Henry Havey, the Business Development Manager of Collagen & Gelatin at haveyh@ajiusa.com to request a sample of High Molecular Weight (HMW) dried fish gelatin.

*Fish gelatin sample acquired by the lab in a 500 gram sample bag*

They provided me with a 500- gram sample at no cost and confirmed it was a Type A fish gelatin with a 0-bloom strength. Henry Harvey can also provide a pricing quote should you be interested in ordering a full supply which comes in 25 kg packs. They also provided the following product data info sheets:

HMWD-Tech-Sheet Download

While I still covet my isinglass cast films I created from boiling dried fish bladders, as well as our mammalian photographic grade type B gelatin, this HMW fish gelatin is a welcome addition I’ve added to my tool kit.

Ashleigh Ferguson Schieszer [CHPL] – Special Collections Conservator, Co-Lab Manager

Bibliography:

Dudin, M. The Art of the Bookbinder and Gilder. Trans. by Richard Macintyre Atkinson. Leeds: The Elmete Press, 1977, p. 51. (Originally 1772)
Foskett; An investigation into the properties of isinglass, SSCR Journal; The Quarterly News Magazine of the Scottish Society for Conservation and Restoration, Volume 5, Issue 4, November 1994, pages 11-14
Nanke C. Schellmann, Animal glues: a review of their key properties relevant to conservation, Reviews in Conservation, No. 8, 2007, pages 55-66
Petukhova, Tatyana. A History of Fish Glue as an Artist’s Material: Applications in Paper and Parchment Artifacts, The Book and Paper Group Annual, Vol. 19, 2000
Soppa, Karolina; Zumbuhl, Stefan; and Hugli, Tamara, Mammalian and Fish Gelatines at Fluctuating Relative Humidity, AIC 51^st Annual Meeting, 2023
World Sturgeon Conservation Society, A Quick Look at an Ancient Fish, 4^th International symposium on sturgeon, Oshkosh, Wisconsin, July 8-13, 2001

Interested in starting a career in conservation? Join us!

The Preservation Lab, a partnership to preserve and conserve the collections of the Cincinnati & Hamilton County Public Library and the University of Cincinnati Libraries, seeks applicants for a Conservation Assistant position.

The Conservation Assistant is a technician level position with on-the-job training that may appeal to emerging conservation professionals. This position will join a collaborative team of 7 full-time staff members, including conservators, a preservation librarian, technicians, student workers and volunteers to preserve collections from both institutions. The Preservation Lab staff consists of both Cincinnati Public Library and the University Library members. This position is a Cincinnati and Hamilton County Public Library position but is stationed at the University of Cincinnati West campus.

The successful candidate will demonstrate the ability to execute hands-on work with skill.

Founded in 1853, the Cincinnati and Hamilton County Public Library today is one of the busiest and most highly acclaimed library systems in the United States, providing service to over 800,000 residents through a network of 40 branch libraries, a major downtown Main Library, and a Distribution Center. CHPL holds one of the largest genealogical collections in the United States and many other specialized collections, most of which are housed in the Main library.

Pay rate begins at $15.87/hour.

Deadline to Apply: Dec 1, 2023

For more information about job duties and how to apply, please visit the Cincinnati and Hamilton County Public Library website.

Ashleigh Ferguson Schieszer, Special Collections Conservator [CHPL]

Save the Date and celebrate Ask a Conservator Day with us – Friday, Nov 3rd

Tune in Friday, November 3rd on our Instagram and ask us anything you might want to know about conservation, preservation or the Lab!

Facing Anyone?!

Back in October of 2022, The Preservation Lab had the pleasure of hosting Book Conservator, Jeff Peachey, for a week-long workshop on Conservation of Leather Bindings. One of the topics that was mentioned, but not discuss in depth, was leather facing.

No one in the lab had ever faced leather before, so Sr. Conservation Specialist, Jessica Ebert, and I decided to conduct some tests to understand the process, the best materials, and tools. With the research available, Jessica and I focused primarily on two sources, Conservation of Leather and Related Materials by Marion Kite and Roy Thomson and an article written by James Reid-Cunningham entitled Leather Rebacking, for the Seminar in Standards of Excellence in Hand Bookbinding, The Guild of Book Workers, 2013.

The primary reasons for testing out this technique was the fact that there were leather books from UC’s Archives and Rare Books Library here in the Lab for treatment and they could potentially be good candidates for leather facing.

Let the tests begin!!

Both Jessica and I chose two different withdrawn leather books to test on:

A tight back leather book
A leather book with false raised bands and a hollow tube

A book in a press — Catarina’s test model (tight back) before facing.

Book in press awaiting treatment — Jessica’s test book model (tight back) before facing.

Catarina’s test model (hollow tube with false raised bands) before facing.

Jessica’s test model (hollow tube with false raised bands) before facing.

The first step was to consolidate the leather on all the withdrawn books we were using as models. The leather was consolidated with 3% Klucel G in isopropanol. Since there were different methods shown in the available resources regarding leather facing, we decided to use two different methods for facing: facing with Japanese tissue adhered with Klucel G and facing with a Crompton heat-set tissue activated with ethanol. Trying out these two different methods would help us to understand which one of these materials would work best and cause less damage/staining to the leather.

Catarina’s Test Models

After having consolidated the leather, the spine was “divided” in two sections, top and bottom, with a small portion of the spine in between. The reason the spine wasn’t fully faced was because I wanted to see if there were any changes in the leather after being faced, removed, and reattached.

Leather consolidated with 3% Klucel G in isopropanol.

For this book, the leather was very degraded, and I couldn’t get the Japanese tissue to adhere to the leather spine with Klucel G. As a result, for this model I only used the Crompton heat-set tissue method.

The adhesive on the heat-set tissue was activated by brushing on a thin layer of ethanol. Once it was activated, the heat-set tissue was placed on the spine, and with a tamping brush pressed on the leather. Using a lifting knife, I was able to remove the leather spine, leaving the middle portion still adhered to the text block for comparison.

Two portions of the spine fully removed.

Leather spine removed, and two portions of the spine faced.

Once the leather spine was removed, I relined the text block spine with a reversible layer of Japanese tissue and wheat starch paste. The two portions of the leather spine were lined from the back with Japanese kozo fiber tissue and wheat starch paste.

At this point, there were two different ways to follow, I could adhere the faced spines to the text block and then remove the heat-set tissue, or I could remove to heat-set tissue first and then adhere the leather spine to the text block. I decided to first remove the heat-set tissue by activating the adhesive again with ethanol and gently removing it with a Caselli spatula. Once the heat-set tissue was fully removed and the leather was dry, I reattached each portion of the leather spine to the text block with wheat starch paste.

Completed book in press — Two portions of the leather spine adhered to the text block spine.

For the leather book with false raised bands and hollow tube, the process was very similar. However, for this model I was able to try out both the Japanese tissue adhered with Klucel G as a facing method and the Crompton heat-set tissue.

Book in press and the spine being removed with a lifting knife. — Test book model with false raised bands and hollow tube.

The spine was “divided” in two sections: top portion was faced with Crompton heat-set tissue activated with ethanol and the bottom portion of the spine was faced with Japanese kozo fiber tissue adhered with Klucel G.

Using a Peachey lifting knife, I was able to remove both portions of the spine. On the top portion of the spine, I ended up not removing the previous hollow tube, but removed it completely on the bottom portion of the spine.

book in press with the spine removed — Leather spine was removed. The hollow tube was not removed on the top portion of the spine and removed completely on the bottom portion of the spine.

Leather spine removed and facing intact — Two sections of the leather spine faced with different methods.

Once the two portions of the spine were removed, a new hollow tube was created to adhered to the bottom portion of the text block spine. The hollow tube was mode of Griffin Mill Broadsheet 60 gm/115 gm paper. The new hollow tube was adhered with wheat starch paste.

Again, I decided to remove the facing tissue before adhering the leather spine back on. With ethanol, I was able to remove the facing tissue from both pieces of the spine. As seen in the pictures below, while removing the Crompton heat-set tissue there was some loss of the leather along the edges and where the leather was most degraded already.

New hollow tube adhere to the bottom section of the spine.
Removing the Crompton heat-set tissue with a Caselli spatula and ethanol.
Removing the Crompton heat-set tissue with a Caselli spatula and ethanol.

Each spine piece was lined on the verso with a Tengujo tissue and wheat starch paste. This provided some support to the fragile leather spines. The two pieces of the spine were then adhered back on with wheat starch paste.

Leather spine after being faced, removed, and reattached.
Leather spine after being faced, removed, and reattached.

Jessica’s Test Models

Here are a few of Jessica’s test models (she has a better eye for taking good photographs throughout the process).

Tight back leather binding before facing.
Spine faced with Japanese tissue adhered with Klucel G and with Crompton heat-set tissue.
Mid process, spine fully detached.
Two sections of the spine faced with different materials.
Tight back test model after facing.

Final Thoughts…

This was a great project that Jessica and I worked together. It was useful to test out different methods using different types of books with leathers in various stages of deterioration. We learned that Japanese tissue may not be able to be used as a facing material when coated with Klucel G, since in one of the tests I did, it did not adhere to the leather. This could lead to further testing, perhaps working with a Klucel G of a different concentration since we only used a 3% concentration for these tests. In addition, depending on how degraded the leather is, using a Crompton heat-set tissue may not be an ideal good solution for every item as it created some damage on the surface layer of the leather spine of our of the test books. Finally, at least in one of my models, the leather became darker than it was originally. There is still more testing and practice to do before we use this technique on a collection item, but this was a great place to start.

Catarina Figueirinhas [UCL] —- Assistant Conservator

Online Treatment Presentation: Join us April 10th!

To celebrate the upcoming festival of Passover, please join Hebrew Union College and the Preservation Lab for a virtual presentation about the treatment of one of the earliest printed illustrated Haggadot in the rare book collection of the Klau Library.

Tzafun: The Behind the Scenes Work of Repairing the 1526 Prague Haggadah

Overall of opening before treatment
View of broken sewing and poorly aging repairs before treatment
Overall view of leather binding before treatment

Dr. Jordan Finkin, Rare Book and Manuscript Librarian and Co-Director at Hebrew Union College Press will kick off the talk with a discussion about the significance and history of the Haggadah in the greater context of Haggadot Jewish book printing.

Ashleigh N. Ferguson Schieszer, Rare Book and Paper Conservator, will follow by describing the intricate process required to restore the binding and its contents. In this session, Ashleigh will discuss how she met the challenges facing her with this amazing historical work to reverse earlier poorly-done repairs. These treatments were conducted over several years, and included preservation of handwritten songs later added to the Klau’s copy.

Please join us at 11 am on April 10th, 2023 for the hour-long session by registering for the event here.

Check out the recorded session, now available on the HUC-JIR YouTube channel here.

This project was funded by the generous donations of Dr. Valerie Hotchkiss and Dr. David Price.

To learn more about Hebrew Union College (HUC) and to check out their ongoing events, please visit HUC’s website at https://huc.edu/libraries/library-events/.

Ashleigh Ferguson Schieszer, Conservator [CHPL]