Photo-chemical Fascinations, Part 2: Valence Bands & Parking Lots

Previously, we talked just a little bit about halides, and how they fit into the formation of silver gelatin-based images. Today, we’re going to take a closer look at part of the “how.”

Let’s begin with a brief overview of the darkroom process. As a reminder, the mechanics of creating a black and white print generally include the following steps:

  1. A paper is pre-coated with a halide salt and silver nitrate that are mixed in a binder such as gelatin.
  2. An image is first generated by projecting a source of illumination (like the sun or a lamp) through film onto a coated piece of paper. 
  3. Next, the paper or film is developed in a bath of chemicals.  This is the part of the process the image seems to “magically” appear!
  4. The image developing chemical reaction is stopped in a “stop bath.”
  5. The paper or film is moved to a second bath to “fix” the image in a fixative bath.
  6. The photograph is rinsed and hung to dry – ready to safely see the light of day.

Now, let’s delve a little deeper into the chemical reaction described in step two, beginning with a bit of a thought experiment. If I say to you, “semiconductor,” what springs to mind? Something involving electronics, perhaps? Maybe chips, lots of little circuits and tiny wires? Maybe, if you’re more photography-minded, a digital camera? All excellent things to think of! With this in mind, what if I told you that our silver gelatin emulsion is also a semiconductor, one that converts light into latent images instead of electricity?

Well, that is what we’re going to explore today, the basics of the mechanism by which light gets our emulsion ready to record latent images. The light shines on an atom (in this case, our silver halide ion), energy is transferred to an electron, and the electron moves to an excited state and is ready to make chemical magic.

If you refer back to your basic chemistry, atoms are composed of three parts: protons, neutrons, and electrons. Protons are positively charged and reside in the nucleus (center) of an atom with chargeless neutrons. Negatively charged electrons orbit the nucleus in bands. When all things are equal, an atom has the same number of protons as electrons, leaving the atom neutral. There aren’t a lot of atoms that are naturally like this, however; an atom will often have too many or too few electrons in orbit. This is a good thing, as it not only makes them stable, it makes them available for bonding with other atoms and creating chemical reactions.

Now let’s apply some of that to our silver halide. The electrons near the nucleus of our ion are in the “ground” state. They’re unexcited. The nucleus has them firmly gripped in its gravitational pull and they’re uninterested in going anywhere. This area of grounded electrons is known as the valence band. In order for them to be available for any sort of exchange, they’ll need to get farther away from that nucleus, and out into an outer band of the ion, conveniently known as the conductance band.

How does this all relate to the parking lots I mentioned in the title? I’m glad you asked. The parking lot analogy is a fantastic illustration of the process by which light interacts with matter. Let’s think of it this way: the nucleus of the silver halide ion is your typical Big Box Store. Directly outside of the store is the valence band parking lot, full of electron cars, all off, all waiting in the ground state. Beyond the parking lot is a strip of grass, which we’ll get to shortly, and beyond that is the conductance band (i.e, the road), where the cars are all in motion, on their way to any number of places.

Valance Bands illustration
The parking lot analogy, illustrated, from AIC’s Photographic Chemistry for Preservation, unit 2, “The Latent Image.”

In order for the cars to get out of the valence band, they’re going to need some energy. For our electrons, the needed energy is light. Once they get light to get the engines going, they can pull out of the parking lot and onto the road and drive off to chemical reactions.

Now let’s detour briefly to that grassy strip that I mentioned earlier. It’s known as the forbidden gap. Ideally, this area is empty. However, due to defects such as insufficient energy, an electron may not be able to completely cross to the conductance band, and may be temporarily stuck in this gap. Even here they can be useful as stepping stones for other electrons that need to cross over. Stuck electrons will either receive more energy to get them to the outer bands, or they’ll lose energy and be pulled back to the valence band.

I’ll note here that this structure is characteristic of all semiconductors, including digital camera sensors. In silver halide grains, this excitement of electrons will always happen when it comes into contact with light, as silver halide has a light sensitivity of 100%. No matter what, when a grain of silver halide is exposed to light, it will always liberate an electron. You also needn’t think of it as just one electron at a time being excited in this fashion. The grain can have so much energy that its valence band is completely empty, and vice versa.

What happens after this? Well, that’s an exploration for next time.

Hyacinth Tucker (UCL) — Bindery and Conservation Technician

Bite-Sized Takeaways From Photographic Chemistry Study

Introduction and a Little Something About Halides

About two years ago, I set upon a mission to gain expertise in the area of identification and treatment of photographic materials. Under the guidance of our conservator, Ashleigh, I developed an education plan that was split between the theory of learning the ins and outs of photograph identification, and the hands-on work of treating pieces that came into the Lab. Of course, these two things go hand in hand. If you can’t identify a piece, you can’t treat it correctly, right?

Fast forward to last year. With the start of the pandemic and the transition to working from home, my education plan changed radically. If I’m not in the Lab, I can’t spend much time on treatment, so I had to get a little creative and work on other ways to learn more.

Enter the American Institute for Conservation’s self-study series on Photographic Chemistry for Preservation. It involves eight fairly in-depth units on silver-based analog photographs, how they are created, and as a consequence, how they age and deteriorate.  

I am about halfway through the series; a triumph for me, as I have never been one for the study of chemistry. I will say that while it is still very technical, I’ve had a lot of good pegs to hang the information on, owing both to my earlier studies in photograph conservation and my personal history with film photography. It’s been a tremendous thing, viewing things that I learned as a photography student from a different angle. So far, it’s been a great journey. 

In this series, I will share with you some of the most fascinating things that I’ve learned so far. My aim will be to keep the technical as simple as possible, for those of you who are like me, still coming to terms with the deeper science. The small bites help it all make sense, I promise. Hopefully, you’ll find it all as interesting as I have.  

Before we can understand anything else, we need to talk about halides. What are those and why are they used in photography? Good questions! Halide salts are derived from halogens, which occupy group 7A (column 17) of the Periodic Table of Elements (see below.) Halide salts are used in photographic emulsions that are spread over a substrate (such as paper or film) before the substrate is exposed to light. The silver halides react to the light to form an image when developed.  

I should note here that silver gelatin prints, albumen, and collodion photographs all utilize silver halides in their chemical composition. However, silver gelatin is unique among the three in that it is the only one that uses a true emulsion; in albumen and collodion coatings, the halides rest on the surface.  

In forming the silver gelatin emulsion, halide salts are combined with silver nitrate and water to form silver halides, the compound at the core of silver gelatin photography. Silver nitrate is pretty much universally used regardless of halide salt, as it is water soluble (it dissolves) but not too much so. The freed silver will look for a bond partner, and the halides in halide salt fits the bill.  As a result, silver nitrate, when combined with a halide salt in water, will result in silver halide and a left over salt.  

This reaction, which seems like a lot, I know, is referred to for our purposes as “The Emulsification Equation.” To refresh our memories a bit, an emulsification is a liquid (here, gelatin) that contains fine particles of another liquid (the silver halide) without fully combining. Think mayonnaise, or butter. (This isn’t perfectly analogous, as silver halides are crystalline solids and not liquid fats, but the basic idea is the same.) 

Chemically speaking, that reaction looks like this: 

Equation for emulsification

As a quick reminder, Ag = silver, N = Nitrogen, O = Oxygen, K = Potassium, and Cl = Chlorine. 

Now, if you’ll look at the image of the halogen column of the table below, you’ll see a number of options for salts to combine with silver nitrate. Older emulsions involved bromine or iodine; more modern emulsions tend toward chlorine. Crystals formed from silver chloride salts are much more uniform in structure, which makes its use outcomes much more predictable.  

Salts that will combine with silver nitrate

I’m sure you’ve noticed that we’ve got a couple of halogens unaccounted for, namely fluorine and astatine. Neither of these are used for this kind of work, and for good reason. Fluorine, for its part, is very water soluble. Very water soluble. To put it in perspective, sodium chloride (regular table salt) is about 35% water soluble. I’m sure that in the course of cooking, we’ve all dissolved salt in water, and you can recall how relatively simple that is to do, though not without some small effort. Well, fluorine salts are about 172% water soluble! You could use it for your emulsion, but moments after developing an image in a water-based solution, you’d see it dissolve before your eyes.  

I’ll note here very briefly that chlorine, bromine, and iodine are also more soluble than table salt, but not nearly as much as fluorine, making them perfect partners for our silver ions.

Meanwhile, astatine is…well, it’s radioactive. I think you can see the problem with this one.  

And there you have it, a short and hopefully painless explanation of the humble halide in silver-based photography. In the coming months, we’ll be looking at other fascinating aspects of halides and our Emulsification Equation.  

Hyacinth Tucker (UCL) —- Bindery and Conservation Technician

New YouTube Channel + Our Virtual Lab Tour Recording

The Preservation Lab now has it’s own YouTube channel!! We have a selection of videos including how-to videos, such as How to Make a Non-adhesive Paper Slipcase or Sewing an Unsupported French Link Stitch, and treatment, documentation and outreach videos, like Preserving Your Personal Library or RTI Capture Session of a Large Cuneiform Tablet.

One of our most recent additions to our channel is the recording of our Virtual Lab Tour and Live Q&A, hosted by the Cincinnati & Hamilton County Public Library, which took place on Tuesday. If you weren’t able to join us live, please take a look; it was a very fun event and we had so many great questions from our live viewers.

Make sure to subscribe to our channel so that you can stay up to date on any new videos we add! And don’t forget to like videos, and we’d love to hear about what you’d like to see more of from us in the future.

Jessica Ebert (UCL) – Conservation Tech & Photographic Documentation Specialist

Save the Date: Virtual Lab Tour 1/26 at noon!

The Lab will be offering a virtual lab tour on Tuesday, January 26th at noon (EST).  The Facebook Live event will be hosted on the Cincinnati & Hamilton County Public Library’s Facebook page.  Staff will give a tour of all of our most used and loved areas of the lab and will highlight how we use the spaces and the equipment, tools, and supplies stored in each space.  Following the tour, we will be doing a live Q&A where you can ask us any questions you might have.

We hope you can join us for our first Virtual Tour, but don’t worry if you can’t, a recording of the tour will be available after the event so that you may view it at your leisure.

Jessica Ebert (UCL) – Conservation Tech/Photographic Documentation Specialist/Student Supervisor

The Split-Board Binding: Extensive Yet Extremely Effective

We recently shared a blog post on the Cincinnati & Hamilton County Public Library’s blog that serves as a companion post to this one.  Both posts focus on the repair of two CHPL books, Covered Bridges and When Art Meets Design, that received split-board binding treatments carried out by Kasie.  While this post focuses on the treatment itself, the other illustrates the journey of a circulating book through treatment in the lab (and at home) and its eventual return to the library.  We highly recommend checking out A Journey from Broken to Mended: Repairing Books in the Preservation Lab

As a hybrid conservation lab, we treat and house both special collection items and general circulating collection items, as well as everything in between.  Special collection items are rare or archival materials that typically do not circulate; basically, books and other objects that you can’t take home with you, are out of print, valuable, and/or are less readily available locally, nationally or even globally.  General circulating collections are typically books that can be checked out and taken home, and tend to be newer books, books still in print, and/or more popular books.  Since we are a collaborative lab that means that we treat and house special collections and general collections from both the University of Cincinnati Libraries (UCL) and the Cincinnati & Hamilton County Public Library (CHPL). 

Due to the nature of these two types of collections (general and special), the treatment, documentation and who treats what is very different. Before the pandemic, most of the staff’s time was dedicated to special collection items or the items that fall between the two categories, which we call medium rare, and our students and volunteers, with plenty of hands-on, one-on-one training, handled the bulk of our general collection repairs.  But then working from home, all or a majority of the time, became the norm for Lab staff and we had to shift focus and turn to taking on more general collection repairs that we could more easily take home with us.  Initially, we took home more difficult sewing projects and mending projects that our students or volunteers either hadn’t gotten to yet or were avoiding for one reason or another.  Then, after we could return to the Lab in some capacity to prep our own materials, we realized that split-board bindings* were the ideal general collections treatment for staff to work on from home. 

A split-board binding is a new binding or case that incorporates several newly added reinforcement elements that are then sandwiched between two pieces of board that make up the front and back covers. 

Split-board bindings are a great solution for oversized, heavy books like coffee table books and art books with glossy pages, which are very common in both UCL and CHPL general circulating collections.  They are also, by far, the most complex general collections treatment we perform in the lab and have always been done by the conservation technicians, instead of our students or volunteers. This is not only because of the complexity of the treatment, but also because of the lengthy treatment time involved; a student or volunteer’s limited weekly schedule in the lab is not conducive to such an extensive treatment.  Though it was a general collections treatment reserved solely for the conservation technicians, prior to March 2020 the techs unfortunately had little time to work on these treatments, as our focus was primarily on special collections treatments and housing.  Therefore, we had amassed a little backlog of split-board binding treatments – enter quarantine and working from home! 

One question that might come to mind, if split-board bindings are so elaborate and extensive, why do them on general collections items at all?  Why not just buy a new copy; wouldn’t that be more cost effective?   Typically, the books that warrant a split-board binding are more pricey, glossy paged, oversized books, like art and architecture books.  And unfortunately, though these books have a much higher retail price than your average James Patterson novel, the construction is generally less than ideal.  These books might have beautifully printed, full-color, thick and glossy pages and dynamic cover art, which makes them attractive to the reader, but they also are often sewn with very thin, fragile thread that easily breaks.  The spines are generally lined with a layer of rigid plasticized glue that can become very brittle over time.  Often, the covers or cases are constructed solely of printed paper, not cloth, and generally have a thick piece of board along the spine (which we call a flat back) that doesn’t allow the book to flex properly when opened and can actually make the spine break down and tear in record time.  It is not uncommon for these books to have little to no reinforcement in the attachment of the textblock to the binding (i.e. how the block of pages is attached to the cover), which makes the heavy textblock break away from the cover quite easily with use.

But why are these books constructed so poorly?  These large coffee table and art books are constructed with individual use in mind, not with the frequent use and circulation that comes with a library collection item.  The split-board treatment, along with many general collection repairs, improves on a bad binding design and makes the book stronger and sturdier, using better binding techniques and materials that can better stand up to use by many library patrons. 

A split-board binding treatment involves creating a new binding with new sewn-on endsheets that are reinforced with cloth, at least three sewn on linen tapes (supports), new spine linings, and a new quarter bound case created with two boards at the front cover and two at the back cover, and generally an inlaying of the original cover designs.  However, additional elements of treatment may be warranted based on the condition of the book, such as broken sewing, tears, detached leaves, etc.  The steps generally proceed in the following order: 

  • Prepare materials in the Lab – new endsheets, starched reinforcing cloth, linen tapes, spine linings, binders board, bookcloth and Bristol board for inlays. 
  • Detach textblock from cover, if needed.  
  • Remove original spine linings, mechanically and with poultices.  
  • If broken, remove original sewing thread and disbind textblock.  
  • Mend any tears and guard any separated, torn or detached leaves.  
  • Sew to include linen tape supports and new endsheets using French link stitch – whether partial/added sewing over the original sewing or complete resewing is dependent on whether the original sewing was intact or if it was broken and the textblock disbound. 
  • Round and back spine, as needed.  
  • New spine linings adhered to the spine:  
    • Reversible layer of kozo fiber tissue with wheat starch paste.  
    • Original stuck-on endbands, if present, or new endbands.  
    • Cloth reinforcement lining (Cambric) with flanges that extends past the spine on both sides.  
    • Several paper linings to further support the textblock.   
  • Create “laminated flanges”, the key characteristic of a split-board binding, using the sewn on linen tapes, the flanged cloth piece adhered to the spine, and the first and last leaves of the new endsheets.  Cut laminated flanges into thirds, with the center portion incorporating all the linen tapes.  
  • If the original covers included artwork that should be retained, mechanically remove from the original boards.  Remove remaining board backing with poultice.  
  • Remove and clean the original spine.  
  • Cut binder’s board to size – 2 pieces of board are cut for both the front and back covers (4 pieces total).  The thickness of the boards used is dependent on the shoulder of the book.  
  • Determine placement of the board and adhere the middle laminated flange segment to the top of inner board, keeping the top and bottom laminated flange segment under the inner board, unattached.  Adhere the outer board to the inner, thus sandwiching the middle laminated flange section between the two boards.
  • If the original cover is being inlayed, create and attach an inlay border of thin Bristol board to the cover boards, as needed.  
  • Covering the boards:  
    • Attach the spine cloth piece and turn in at the head and tail.  
    • Attach the board cloth to the upper and lower boards and turn in the edges.  
  • Bevel the remaining laminated flanges and sewn on cloth reinforcement (Cambric) slightly and attach both, in sequence, to the inner boards.   
  • Adhere the pastedowns and trim the remaining sewn on Cambric to roughly 1/8” – ¼”.  
  • If there are cover inlays, adhere the inlay(s) to the cover(s) within the inlay border.  
  • Adhere the original spine to the new spine of the case. 

When completed the treatment offers a substantial amount of support to the textblock and a robust attachment of the textblock to the new case.  While it is an involved treatment that requires a good amount of preparation, work and skill, the end results are worth it all, and the improvements are significant. 

Treatments of this magnitude take many, many hours over the course of several weeks. Often, only a few steps of the treatment can be accomplished at a time to account for drying time, and timing out visits to the Lab. To take a sneak peak at what some of the steps of treatment look like please check out the video below:

For an example of how Kasie used a split-board binding treatment and modified it for a special collection item that came to the Lab from UC’s Winkler Center without a case, check out her blog, A Monster of a Treatment

We hope you’ve enjoyed this peek into a split-board binding treatment!  If you did and you want to see more of what we do, and see the Lab, then please check out our Virtual Lab Tour which will take place on Tuesday, January 26th at noon, live on the Cincinnati & Hamilton County Public Library’s Facebook page.  For forthcoming information about the Virtual Tour follow the Public Library on Facebook and follow the Lab on Instagram (@thepreservationlab). 

*This treatment was originally designed at the Brigham Young University lab. Then it was brought to the University of Kansas lab by Brian Baird, where our conservator, Ashleigh Ferguson Schieszer, learned the treatment and thus brought it to the Preservation Lab.

Kasie Janssen (CHPL) – Senior Conservation Technician & Jessica Ebert (UCL) – Conservation Technician

Button Hole Stitch Binding

Every year our staff, students and volunteers look forward to our Student & Volunteer Appreciation day, which we affectionately call “fun day”. It generally takes place in late November or early December, always before finals week. It is a time to show our appreciation for all the hard work our students, volunteers and staff do throughout the year, while having an opportunity to come together and learn some new bookbinding or book arts technique. In the past, we’ve done paper marbling, made handmade paper, created German long stitch binds, and more.

I have been coordinating our student & volunteer appreciation days for almost as long as I’ve been in the Lab, so for at least 12 years now. I love it because I am the type of person who enjoys planning these types of things, but also I love watching a student, volunteer or staff member just get really excited about something new. You never know if it’s going to be that quiet new volunteer who just can’t get enough of paper marbling, or that student who doesn’t have any art background but just does the most amazing pulp paintings ever! So after all these years, the thought of 2020/the pandemic ruining everything and not having any sort of student/volunteer appreciation day was just unacceptable!

I immediately thought, “What types of activities could we do virtually that would be no cost to the lab and would give everyone a couple hours to come together and decompress?” After a little brainstorming with Holly, we came up with a Button Hole Stitch binding (which I had recently learned) and a simple dissolving view. With the help of my wonderful student staff member and cohort buddy, Lexie, I prepped kits for our virtual event, as well as prepared a step by step video on creating a button hole stitch binding.

Here are some of the beautiful creations that came out of our little virtual fun day:

If you would like to make your own Button Hole Stitch book check out our video on the Preservation Lab MediaSpace channel:

For the dissolving view we used Green Chair Press’ handy template, which you can find here in their blog post on dissolving views.

Jessica Ebert [UCL] – Conservation Tech/Photographic Documentation Specialist/Student Supervisor

No-stick protective Mylar jacket for CD compilation

The purpose of this blog is to show a relatively easy long-term solution for strengthening and protecting the packaging for shallow banker’s box enclosures. There are two notable benefits to using this solution. The first being that in some cases little to no repairing needs to be done to damaged parts of the box and the second is at no time does any adhesive come into contact with the original piece. I have developed this system down to a science. If I make my measurements correctly, from start to finish, the lid and base jacket can be made from the custom stencils in about 180 minutes.

Ultimately you’ll be cutting 2 pieces of 4 mil Mylar to the following dimensions (W+thx4+4inches x H+thx4+4 inches) with the help of stencils.

To make a stencil I just place the lid in the center of the wastepaper and adding about 1mm all around, trace the width and height. Add 1 wall thickness all around followed by 1 wall board thickness all around then another wall thickness all around. Draw each of these added lines all the way to the edge of the paper.

Template of mylar jacket

You may notice little adaptations to the tabs that will be cut out of the Mylar. I make the tabs on opposite sides to create symmetry. Here is a close-up of one.

After scoring and cutting out the Mylar to match the pattern, fold on the lines using either a ruler and bone folder or your fingers.       

When you are all ready, place the box in the center of the Mylar sleeve and place double stick tape where the tabs will secure the corners. Start with the outside corners first.

One of the great qualities of this protective wrapper is that it can cut out repair time by the virtue of the strength of the wrapper itself.

Secure the rest of the outside, then inside corners, and we’re done!

Now it’s time to enjoy the music.

Chris Voynovich (CHPL) — Senior Conservation Technician

Poisonous Book Project

In the Victorian era, textiles were colored with a green copper aceto-arsentite, used from 1814 to the late 1800’s.  (Side note: this green is sometimes referred to as Paris green or emerald green and was widely used by impressionist painters.)  And since books were bound in textiles, it’s no surprise that these vivid green cloths were used to bind publisher’s bindings.  Therefore, it’s entirely possible that these copper arsenic covers are lurking within our library collections dating to the 19th century.  In 1855, Viridian green was invented which eventually replaced Paris Green; therefore, green cloth bindings from the 20th century to today are of likely no concern.

So how do we know if a binding is poisonous?  Until recently, there hasn’t been a lot of published research on the subject.  The ability to perform scientific analysis testing is required, such as the use of XRF (x-ray fluorescence elemental analysis). See this article for more info: https://theconversation.com/how-we-discovered-three-poisonous-books-in-our-university-library-98358.

When faced with the question of how to ID these textiles in the past, I’ve referred researchers to textile conservators who may be more familiar with this subject – as well as paintings conservators since they deal with pigments on a regular basis.  The best resource on the subject I could track down was an adjacently-related conservation study on Navajo Textiles, titled, Coping With Arsenic-Based Pesticides on Textile Collections by Jae R. Anderson, Nancy Odegaard, Martina Dawley, Delana Joy Farley, and Werner Zimmt from the American Institute for Conservation ‘s Objects Specialty Group Postprints, Volume 21, 2014.

However, new research being conducted by Melissa Tedone and researchers at Winterthur Museum, Garden & Library shines new light on the subject. They provide helpful recommendations on ID, handling, and storage.  Please see https://www.iiconservation.org/content/poison-book-project to learn about the Poisonous Book Project being performed by Winterthur Library.

https://www.iiconservation.org/content/poison-book-project

While our lab does not currently perform x-ray fluorescence spectroscopy to confirm whether a book is poisonous, there are some visual clues to be aware of.  When handling a copy of Rustic Adornments for Homes and Taste (1857) Melissa Tedone notes how “the bright green colorant flakes readily from the bookcloth with even the gentlest touch of my porcupine quill.”  This pigment seems to be impregnated into the cloth rather than dyed, and therefore prone to brittleness and flaking.

Recommendations to those without the ability to ID pigments: If you suspect that your book may be bound within the Victorian era of the 19th century, treat the book as though it may contain arsenic.

  • Place it in a polyester or polypropylene jacket and house it inside an enclosure.
  • Handle it with gloves that are disposable or are washable
  • When handling, lay it out on a table with paper liner that can be disposed of after use (or clean the table after use)
  • If you are in need of a box for storage, University Products and Talas are great resources for purchasing archival housing supplies.

Additional recommendations for libraries by Melissa Tedone and the Winterthur crew include:

  • Digitize bindings to provide researchers a non-toxic option of handling these texts
  • Identify and store these books together in one location within collections storage.  If these materials are affected in a potential flood or disaster, this will help to streamline handling and containment of these dangerous materials. 

Curious to know if there are specific titles of books that have tested positive for “poison?” Check out this link for a table of books identified by the Poisonous Book project and compare against duplicate titles in your collection:

See http://wiki.winterthur.org/wiki/Poison_Book_Project

Screenshot of the http://wiki.winterthur.org/wiki/Poison_Book_Project
http://wiki.winterthur.org/wiki/Poison_Book_Project#Arsenical_Books_List

Since testing continues, the Winterthur research team has created a color swatch bookmark to assist with identifying potentially arsenical green bookcloth.  The library asks for the consideration of of $5 or more to help cover printing and mailing costs. Email reference@wintherthur.org for more information.

To learn more, check out the 2023 Connecting to Collections (C2C) Care Webinar The Poison Book Project.

Ashleigh Ferguson Schieszer (CHPL) – Rare Book and Paper Conservator, Lab Co-Manager

List of Resources:

https://www.iiconservation.org/content/poison-book-project

http://wiki.winterthur.org/wiki/Poison_Book_Project

https://www.iiconservation.org/content/news-conservation-issue-77-april-may-2020

https://theconversation.com/how-we-discovered-three-poisonous-books-in-our-university-library-98358

https://www.finebooksmagazine.com/issue/arsenic-and-old-books

http://resources.culturalheritage.org/osg-postprints/wp-content/uploads/sites/8/2015/03/osg021-08.pdf

Enclosures and the Kyle Insert

The Kyle Insert, version 2

Last month, I showed you how to make a corrugated clamshell. At that time, I mentioned some alternative strategies for special situations, such as considerations of working space, collection size, etc. Pre-made boxes may be the way to go here. They’re generally non-adhesive, and excellent if you have a large collection that needs help, but can’t be worked on right away, for pieces going to off-site storage, or if you’re in a situation where box building space is at a premium, such as many of our work from home setups (I’m currently working at my kitchen table, which is definitely a squeeze sometimes!) 

There are multiple ways to obtain pre-made enclosures: 

  • Many commercial binderies offer custom economy boxing. Our Lab uses HF Group (http://www.hfgroup.com/) when needed. Their work is excellent, and their enclosures can be created from sent measurements. This is wonderful for housing items in our collection that require storage, but we feel are too fragile to be shipped.  
  • Most major conservation suppliers, such as Talas (https://www.talasonline.com/) and Gaylord (https://www.gaylord.com/c/Conservation-Supplies) offer archival boxes in common sizes.  

A pre-made enclosure can also be a great option for very small items, to keep them from becoming lost on the shelf.  

Under normal circumstances, a box created in the Lab for a small piece would be lined with foam to keep it from moving around in the larger cavity, but when the pandemic hit, we thought it might be a good idea to find ways to do this that didn’t require foam, which might be expensive or difficult to source or store.  

Enter the Kyle Insert. Developed by Kyle Olmon, it is an answer to the ongoing question of new ways to store smaller items that will keep them safe and prevent them from getting lost. It works well for things like artist books, which are often incredibly small. It’s also a time saver in lieu of foams. I don’t know about you, but cutting foam is not my favorite thing. An alternative is always welcome when it is appropriate, and we (and the books!) can always benefit from having multiple ways to solve problems. 

Written instructions from Kyle Olmon are available on-line at https://kyleolmon.files.wordpress.com/2016/05/kyle_insert_v2_instructions.pdf . I found that the insert made more sense to me when I had a visual representation. It’s a surprisingly simple structure but may not seem that way on paper.  In light of that, I did something a little different and put together a video of my assembly efforts, interspersed with instructions and diagrams from Kyle Olmon throughout. Hopefully the video combined with Mr. Olmon’s excellent instructions will help you get started with this form! 

An enclosure with the Kyle Insert.  The insert is a sling like structure that secures a small tux box.  The image is clickable leading to a video documenting the creation of the insert.
CLICK on the image above to open the video, and push play. The video will open in a new tab and may take a minute to load. Link – https://mailuc-my.sharepoint.com/:v:/g/personal/prochah_ucmail_uc_edu/Ec3zHrG3NClHlvMsKDruYyMBTzj-3YmnJeex1-elL98XVw?e=hM1ozt

Hyacinth Tucker (UCL) — Bindery and Conservation Technician

Model making: Italian stationery bind, laminated archival bind

Admittedly the title of this blog is a bit dry, but whenever I see the phrase stationery binding my eyes dart and the corners of my mouth start to move upward. Since trying my hand at an accounting book at Paper and Book Intensive 2017 in Chela Metzger’s workshop Early Modern Record-Keeping Book Structures, I have enjoyed learning more about their variations, creating historical models, and using the form as an inspiration for artist’s books.

After digging into Katherine Beaty’s essay Tackets, Buckles, and Overbands: Italian Stationery Bindings of the HBS Medici Family Collectionthe in the latest volume of Suave Mechanicals (http://www.thelegacypress.com/suave-mechanicals-vol-6.html), I decided to attempt a model of the second largest laminated archival bind. Beaty’s essay provides excellent descriptions of the various accounting books within the Medici collection, helping guide me in the construction of the model and filling in large gaps in my knowledge.

Katherine Beaty’s essay is not a “how to” manual, so all the errors and false assumptions that present themselves in the final model are mine alone. Making this at home with materials I had on-hand provided some challenges, so there are some missteps in terms of historical accuracy. But, in the end I’ll give the final product solid B for effort! And I had a great time making it.

Laminated leather archival binding with buckle fastening, size 34 x 27 cm.

I would love to make the next model better, so shoot me and email (holly.prochaska@uc.edu) with tips and corrections. Here is a somewhat rough draft of my instructions – proceed with joy and cautionhttps://drive.google.com/file/d/10sXW-dRi1XO6cVS8S-5CPBUHH8G_wpMX/view?usp=sharing

Holly Prochaska (UCL) —- Preservation Librarian